Oxidative degradation of chlorinated phenols catalyzed by a non-heme iron(III) complex

被引：28

作者：

Hemmert, C ^{[1
]}

Renz, M ^{[1
]}

Meunier, B ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 137卷 / 1-3期

关键词：

non-heme iron catalyst; monopersulfate; chlorinated phenols; oxidation;

D O I：

10.1016/S1381-1169(98)00131-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new symmetric pentadentate ligand containing four pyridine groups, bis(di-2-pyridylmethyl)amine (BDPMA), has been synthesized in a good yield. The corresponding non-heme iron(III) complex, [Fe(BDPMA)](NO3)(3), with potassium monopersulfate as oxidant, catalyzed the oxidative degradation of aromatic pollutants chlorinated phenols to yield the corresponding benzoquinones. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：205 / 212

页数：8

相关论文

共 15 条

[1] BIODEGRADATION OF CHEMICALS OF ENVIRONMENTAL CONCERN [J].

ALEXANDER, M .

SCIENCE, 1981, 211 (4478) :132-138

[2] REDOX TAUTOMERISM IN HIGH-VALENT METAL-OXO-AQUO COMPLEXES - ORIGIN OF THE OXYGEN-ATOM IN EPOXIDATION REACTIONS CATALYZED BY WATER-SOLUBLE METALLOPORPHYRINS [J].

BERNADOU, J ;

FABIANO, AS ;

ROBERT, A ;

MEUNIER, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) :9375-9376

[3] TRIALKYLSULFONIUM-HYDROXIDES AND TRIALKYLSELENONIUMHYDROXIDES FOR THE PYROLYTIC ALKYLATION OF ACIDIC COMPOUNDS [J].

BUTTE, W ;

EILERS, J ;

KIRSCH, M .

ANALYTICAL LETTERS PART A-CHEMICAL ANALYSIS, 1982, 15 (10) :841-850

[4] SPECTROPHOTOMETRIC DETERMINATION OF CHLORIDE AT PARTS-PER-BILLION LEVEL BY MERCURY(II) THIOCYANATE METHOD [J].

FLORENCE, TM ;

FARRAR, YJ .

ANALYTICA CHIMICA ACTA, 1971, 54 (02) :373-&

[5] MASS-SPECTROMETRIC CHARACTERIZATION OF CARBAMAZEPINE-10,11-EPOXIDE - CARBAMAZEPINE METABOLITE ISOLATED FROM HUMAN URINE [J].

FRIGERIO, A ;

GARATTINI, S ;

BIANDRATE, P ;

MORSELLI, PL ;

FANELLI, R ;

PASSERINI, G .

JOURNAL OF PHARMACEUTICAL SCIENCES, 1972, 61 (07) :1144-+

[6]

HADASCH A, 1998, IN PRESS NEW J CHEM

[7] THE OXIDATIVE 4-DECHLORINATION OF POLYCHLORINATED PHENOLS IS CATALYZED BY EXTRACELLULAR FUNGAL LIGNIN PEROXIDASES [J].

HAMMEL, KE ;

TARDONE, PJ .

BIOCHEMISTRY, 1988, 27 (17) :6563-6568

[8]

HUYNH VB, 1985, TAPPI J, V68, P98

[9] Oxidation of pollutants catalyzed by metallophthalocyanines [J].

Meunier, B ;

Sorokin, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (11) :470-476

[10]

Meunier B., 1994, METALLOPORPHYRINS CA, P133