Orientation and order of β-tetrahexyl-sexithiophene molecules deposited by organic molecular beam deposition

被引:8
作者
Sassella, A
Borghesi, A
Tubino, R
Destri, S
Porzio, W
机构
[1] Dipartimento Sci Mat, I-20126 Milan, Italy
[2] INFM, I-20126 Milan, Italy
[3] CNR, Ist Chim Macromol, I-20133 Milan, Italy
关键词
organic molecular beam deposition; optical properties; structural order; oligothiophene;
D O I
10.1016/S0379-6779(98)00154-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Highly ordered and oriented deposition of substituted sexithiophene molecules is obtained on single crystal organic substrates. The study of X-ray diffraction and of the optical absorption of the films measured under different angles of incidence and with different directions of light polarization permits a complete structural model to be proposed. In addition, some interesting conclusions about the average molecular orientation with respect to the substrate are drawn. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:83 / 86
页数:4
相关论文
共 14 条
[1]  
Borghesi A, 1998, ADV MATER, V10, P931, DOI 10.1002/(SICI)1521-4095(199808)10:12<931::AID-ADMA931>3.0.CO
[2]  
2-#
[3]  
Destri S, 1998, MACROMOL CHEM PHYSIC, V199, P1973, DOI 10.1002/(SICI)1521-3935(19980901)199:9<1973::AID-MACP1973>3.0.CO
[4]  
2-6
[5]   ULTRAHIGH-VACUUM QUASIEPITAXIAL GROWTH OF MODEL VAN-DER-WAALS THIN-FILMS .1. THEORY [J].
FORREST, SR ;
ZHANG, Y .
PHYSICAL REVIEW B, 1994, 49 (16) :11297-11308
[6]   ORGANIC MOLECULAR-BEAM DEPOSITION OF ALPHA-SEXITHIENYL [J].
HAMANO, K ;
KURATA, T ;
KUBOTA, S ;
KOEZUKA, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1994, 33 (7B) :L1031-L1034
[7]   RAMAN-SPECTRA AND LATTICE-VIBRATIONS IN SINGLE-CRYSTALS OF POTASSIUM ACID PHTHALATE [J].
KRISHNAMURTHY, N ;
SOOTS, V .
JOURNAL OF RAMAN SPECTROSCOPY, 1977, 6 (05) :221-226
[8]   ORIENTATION AND STRUCTURE OF SEXITHIOPHENE (6T) FILMS DEPOSITED ON FRICTION ORIENTED PTFE LAYERS [J].
LANG, P ;
VALAT, P ;
HOROWITZ, G ;
GARNIER, F ;
YASSAR, A ;
WITTMANN, JC ;
LOTZ, B ;
MEYER, S .
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1995, 92 (04) :963-966
[9]   Spectroscopic evidence for a substrate dependent orientation of sexithiophene thin films deposited onto oriented PTFE [J].
Lang, P ;
Horowitz, G ;
Valat, P ;
Garnier, F ;
Wittmann, JC ;
Lotz, B .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (41) :8204-8211
[10]   Electronic spectra of self-organized oligothiophene films with ''standing'' and ''lying'' molecular units [J].
Oelkrug, D ;
Egelhaaf, HJ ;
Haiber, J .
THIN SOLID FILMS, 1996, 284 :267-270