Surface characteristics and corrosion behavior of laser surface nitrided NiTi shape memory alloy for biomedical applications

被引:18
作者
Man, HC [1 ]
Cui, ZD [1 ]
Yue, TM [1 ]
机构
[1] Hong Kong Polytech Univ, Dept Ind & Syst Engn, Adv Mfg Technol Res Ctr, Laser Proc Grp, Kowloon, Hong Kong, Peoples R China
关键词
NiTi; laser gas nitriding; corrosion; Ni ion release; biomaterials;
D O I
10.2351/1.1514236
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Laser gas nitriding (LGN) has been applied to fabricate a TiN coating on the surface of NiTi alloy for the purpose of improving the surface properties. The microstructure, surface characteristics, and corrosion properties of the laser gas nitrided layer on NiTi alloy surface were investigated. The nickel release rate of the LGN specimen in Hanks' solution was also investigated. The results of x-ray diffraction, x-ray photoelectron spectroscopy, and scanning electron microscopy confirmed that a continuous TiN layer which is nearly free of nickel has formed on the outermost surface of the substrate. Good metallurgical bonding between the nitride layer and the substrate has been achieved. The corrosion resistance of the LGN alloy in Hanks' solution at 37 degreesC showed significant improvement. The nickel release rate in Hanks' solution at 37 degreesC of the surface nitrided alloy as determined by atomic absorption spectrometry has been decreased significantly. The surface TiN layer was very inert, and no obvious changes in chemical composition and surface appearance were observed after immersion test in Hanks' solution at 37 degreesC for 15 days. (C) 2002 Laser Institute Of America.
引用
收藏
页码:242 / 247
页数:6
相关论文
共 28 条
[1]  
Ayers RA, 1999, J BIOMED MATER RES, V45, P42
[2]   Cytocompatibility of Ti-6Al-4V and Ti-5Al-2.5Fe alloys according to three surface treatments, using human fibroblasts and osteoblasts [J].
Bordji, K ;
Jouzeau, JY ;
Mainard, D ;
Payan, E ;
Netter, P ;
Rie, KT ;
Stucky, T ;
HageAli, M .
BIOMATERIALS, 1996, 17 (09) :929-940
[3]   Corrosion properties of TiN prepared by laser gas alloying of Ti and Ti6Al4V [J].
Garcia, I ;
De Damborenea, JJ .
CORROSION SCIENCE, 1998, 40 (08) :1411-1419
[4]   Analysis of the phases developed by laser nitriding Ti-6Al-4V alloys [J].
Hu, C ;
Xin, H ;
Watson, LM ;
Baker, TN .
ACTA MATERIALIA, 1997, 45 (10) :4311-4322
[5]   Hardness and corrosion protection enhancement behaviour of surgical implant surfaces treated with ceramic thin films [J].
Hübler, R .
SURFACE & COATINGS TECHNOLOGY, 1999, 116 :1111-1115
[6]  
Jones MI, 2000, J BIOMED MATER RES, V52, P413, DOI 10.1002/1097-4636(200011)52:2<413::AID-JBM23>3.0.CO
[7]  
2-U
[8]   Titanium-nickel shape memory clamps in small bone surgery [J].
Musialek, J ;
Filip, P ;
Nieslanik, J .
ARCHIVES OF ORTHOPAEDIC AND TRAUMA SURGERY, 1998, 117 (6-7) :341-344
[9]  
RAHANEN J, 1999, THESIS OULU U OULU
[10]   REVIEW OF CVD TIN COATINGS FOR WEAR-RESISTANT APPLICATIONS - DEPOSITION PROCESSES, PROPERTIES AND PERFORMANCE [J].
REBENNE, HE ;
BHAT, DG .
SURFACE & COATINGS TECHNOLOGY, 1994, 63 (01) :1-13