Rhodium Nanoparticle Shape Dependence in the Reduction of NO by CO

被引：41

作者：

Renzas, James Russell ^{[1
]}

Zhang, Yawen ^{[2
]}

Huang, Wenyu ^{[1
]}

Somorjai, Gabor A. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA

[2] Peking Univ, Beijing 100871, Peoples R China

来源：

CATALYSIS LETTERS | 2009年 / 132卷 / 3-4期

关键词：

Catalysis; Nanoparticles; Nanocubes; NO; CO; Rhodium; Shape dependence; GENERATION VIBRATIONAL SPECTROSCOPY; BENZENE HYDROGENATION; SUPPORTED RHODIUM; SINGLE-CRYSTAL; NITRIC-OXIDE; CATALYTIC-PROPERTIES; RH(111); OXIDATION; SURFACES; KINETICS;

D O I：

10.1007/s10562-009-0144-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The shape dependence of the catalytic reduction of nitric oxide by carbon monoxide on rhodium nanopolyhedra and nanocubes was studied from 230 to 270 degrees C. The nanocubes are found to exhibit higher turnover frequency and lower activation energy than the nanopolyhedra. These trends are compared to previous studies on Rh single crystals.

引用

页码：317 / 322

页数：6

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