共 2 条
A double chain coordination polymer:: {[Zn (H2O)6][Zn(3,3′,4,4′-benzophenonetetra-carboxylate)H2O]•4H2O}n
被引:10
作者:
Yang, YY
Szeto, L
Wong, WT
[1
]
机构:
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
关键词:
zinc complex;
benzophenonetetracarboxylic acid;
crystal structure;
coordination polymer;
D O I:
10.1002/aoc.559
中图分类号:
O69 [应用化学];
学科分类号:
081704 ;
摘要:
The double-chain coordination polymer, {[Zn(H2O)(6)][Zn(bbtc)H2O](.)4H(2)O}(n) (bbtc=3,3',4,4'-benzophenonetetracarboxylate), features two kinds of zinc center. One is octahedrally coordinated by six aqua ligands and the other is coordinated by four carboxylate oxygen atoms, derived from three bbtc ligands, and a water molecule, forming a geometry intermediate between square-pyramidal and trigonal bipyramidal. Copyright (C) 2003 John Wiley Sons, Ltd.
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页码:958 / 959
页数:2
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