Controlled Continuous Patterning of Polymeric Nanofibers on Three-Dimensional Substrates Using Low-Voltage Near-Field Electrospinning

被引:242
作者
Bisht, Gobind S. [1 ]
Canton, Giulia [2 ]
Mirsepassi, Alireza [3 ]
Kuinsky, Lawrence [3 ]
Oh, Seajin [3 ,4 ]
Dunn-Rankin, Derek [3 ]
Madou, Marc J. [1 ,2 ,3 ,4 ,5 ]
机构
[1] Univ Calif Irvine, Dept Biomed Engn, Irvine, CA 92617 USA
[2] Univ Calif Irvine, Dept Mat Sci & Engn, Irvine, CA 92617 USA
[3] Univ Calif Irvine, Dept Mech & Aerosp Engn, Irvine, CA 92617 USA
[4] UNIST, Ulsan 689798, South Korea
[5] WCU, Natl Res Fdn Korea, Minist Educ Sci & Technol, Cullowhee, NC USA
基金
美国国家科学基金会;
关键词
Electrospinning; polymeric nanofiber; micro/nanopatterning; suspended nanofibers; microfabrication; microelectromechanical systems (MEMS); ION SECONDARY BATTERIES; GLASSY-CARBON SURFACE; MOLECULAR-WEIGHT; FIBERS; FABRICATION; SCAFFOLD; FUNCTIONALIZATION; MEMBRANES; ALIGNMENT; ARRAYS;
D O I
10.1021/nl2006164
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
We report on a continuous method for controlled electrospinning of polymeric nanofibers on two-dimensional (2D) and three dimensional (3D) substrates using low voltage near-field electrospinning (LV NFES). The method overcomes some of the drawbacks in more conventional near-field electrospinning by using a superelastic polymer ink formulation. The viscoelastic nature of our polymer ink enables continuous electrospinning at a very low voltage of 200 V, almost an order of magnitude lower than conventional NFES, thereby reducing bending instabilities and increasing control of the resulting polymer jet. In one application, polymeric nanofibers are freely suspended between microstructures of 3D carbon on Si substrates to illustrate wiring together 3D components in any desired pattern.
引用
收藏
页码:1831 / 1837
页数:7
相关论文
共 76 条
[1]
Chemistry on Electrospun Polymeric Nanofibers: Merely Routine Chemistry or a Real Challenge? [J].
Agarwal, Seema ;
Wendorff, Joachim H. ;
Greiner, Andreas .
MACROMOLECULAR RAPID COMMUNICATIONS, 2010, 31 (15) :1317-1331
[2]
Direct-Write Piezoelectric Polymeric Nanogenerator with High Energy Conversion Efficiency [J].
Chang, Chieh ;
Tran, Van H. ;
Wang, Junbo ;
Fuh, Yiin-Kuen ;
Lin, Liwei .
NANO LETTERS, 2010, 10 (02) :726-731
[3]
Continuous near-field electrospinning for large area deposition of orderly nanofiber patterns [J].
Chang, Chieh ;
Limkrailassiri, Kevin ;
Lin, Liwei .
APPLIED PHYSICS LETTERS, 2008, 93 (12)
[4]
Multifunctional Electrospun Fabrics via Layer-by-Layer Electrostatic Assembly for Chemical and Biological Protection [J].
Chen, Liang ;
Bromberg, Lev ;
Lee, Jung Ah ;
Zhang, Huan ;
Schreuder-Gibson, Heidi ;
Gibson, Phillip ;
Walker, John ;
Hammond, Paula T. ;
Hatton, T. Alan ;
Rutledge, Gregory C. .
CHEMISTRY OF MATERIALS, 2010, 22 (04) :1429-1436
[5]
An electrospun poly(vinylidene fluoride) nanofibrous membrane and its battery applications [J].
Choi, SW ;
Jo, SM ;
Lee, WS ;
Kim, YR .
ADVANCED MATERIALS, 2003, 15 (23) :2027-2032
[6]
Patterning of light-emitting conjugated polymer nanofibres [J].
Di Benedetto, Francesca ;
Camposeo, Andrea ;
Pagliara, Stefano ;
Mele, Elisa ;
Persano, Luana ;
Stabile, Ripalta ;
Cingolani, Roberto ;
Pisignano, Dario .
NATURE NANOTECHNOLOGY, 2008, 3 (10) :614-619
[7]
DOSHI J, 1995, J ELECTROSTAT, V35, P151, DOI 10.1016/0304-3886(95)00041-8
[8]
EK ZR, 2008, J ACHIEV MAT MANUF E, V27, P35
[9]
Stretching of a straight electrically charged viscoelastic jet [J].
Feng, JJ .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 2003, 116 (01) :55-70
[10]
Beaded nanofibers formed during electrospinning [J].
Fong, H ;
Chun, I ;
Reneker, DH .
POLYMER, 1999, 40 (16) :4585-4592