Macroporous Co3O4 platelets with excellent rate capability as anodes for lithium ion batteries

被引:144
作者
Lu, Yan [1 ]
Wang, Yong [1 ]
Zou, Yuqin [1 ]
Jiao, Zheng [1 ]
Zhao, Bing [1 ]
He, Yaqin [1 ]
Wu, Minghong [1 ]
机构
[1] Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
基金
中国国家自然科学基金;
关键词
Macroporous materials; Microwave-irradiation; Anode materials; Lithium ion battery; MICROWAVE-ASSISTED SYNTHESIS; HYDROTHERMAL SYNTHESIS; ELECTRODE MATERIALS; STORAGE; NANOSHEETS; NANOTUBES; PERFORMANCE; CONVERSION; CAPACITY;
D O I
10.1016/j.elecom.2009.10.046
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper reports the microwave-assisted synthesis of Co3O4 nanomaterials with different morphologies including nanoparticles, rod-like nanoclusters and macroporous platelets. The new macroporous platelet-like Co3O4 morphology was found to be the best suitable for reversible lithium storage properties. It displayed superior cycling performances than nanoparticles and rod-like nanoclusters. More interestingly, excellent high rate capabilities (811 mAh g(-1) at 1780 mA g(-1) and 746 mAh g(-1) at 4450 mA g(-1)) were observed for macroporous Co3O4 platelet. The good electrochemical performance could be attributed to the unique macroporous platelet structure of Co3O4 materials. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:101 / 105
页数:5
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