Non-Metal-Mediated Homogeneous Hydrogenation of CO2 to CH3OH

被引：426

作者：

Ashley, Andrew E. ^{[1
]}

Thompson, Amber L. ^{[2
]}

O'Hare, Dermot ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England

[2] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 52期

基金：

英国工程与自然科学研究理事会;

关键词：

amines; boron; carbon dioxide; hydrogenation; methanol; FRUSTRATED LEWIS PAIRS; FREE CATALYTIC-HYDROGENATION; HETEROLYTIC H-2 ACTIVATION; CARBON-DIOXIDE; CRYSTAL-STRUCTURES; ORGANIC FRAMEWORK; DIHYDROGEN; PHOSPHINES; REACTIVITY; CLEAVAGE;

D O I：

10.1002/anie.200905466

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(figure represented) Turning a problem to advantage: CO2, a contributor to global warming, was converted into the valuable resource CH3OH by adding it to 2,2,6,6-tetramethylpiperidine and B(C6F 5)3 in toluene under H2 (1-2 atm), heating the mixture at 160°C, and vacuum distillation. CH3OH was formed via the complex shown (C blue, N purple, O red, B orange, F green) as the sole C1 product. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9839 / 9843

页数：5

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