Control of vesicular morphologies through hydrophobic block length

被引:159
作者
Azzam, Tony [1 ]
Eisenberg, Adi [1 ]
机构
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
关键词
block copolymers; hydrophobic effect; polymerization; self-assembly; vesicles;
D O I
10.1002/anie.200602897
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
About the size of it: A series of polystyrene-block-poly(acrylic acid) (PS-b-PAA) block copolymers were developed in which the length of the PAA block was kept constant and the length of the PS block was varied. This allowed a study of the effect of the PAA/PS block ratio on the vesicle sizes as well as on the wall thicknesses. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7443 / 7447
页数:5
相关论文
共 73 条
[1]
Vesicles and liposomes:: A self-assembly principle beyond lipids [J].
Antonietti, M ;
Förster, S .
ADVANCED MATERIALS, 2003, 15 (16) :1323-1333
[2]
Bilayers and interdigitation in block copolymer vesicles [J].
Battaglia, G ;
Ryan, AJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (24) :8757-8764
[3]
Benson Heather A. E., 2005, Current Drug Delivery, V2, P23, DOI 10.2174/1567201052772915
[4]
Molecular weight dependence of polymersome membrane structure, elasticity, and stability [J].
Bermudez, H ;
Brannan, AK ;
Hammer, DA ;
Bates, FS ;
Discher, DE .
MACROMOLECULES, 2002, 35 (21) :8203-8208
[5]
BOURGEATLAMI E, 2003, SURF SCI SER, V115, P189
[6]
Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].
Caruso, F ;
Caruso, RA ;
Möhwald, H .
SCIENCE, 1998, 282 (5391) :1111-1114
[7]
DIRECT COLORIMETRIC DETECTION OF A RECEPTOR-LIGAND INTERACTION BY A POLYMERIZED BILAYER ASSEMBLY [J].
CHARYCH, DH ;
NAGY, JO ;
SPEVAK, W ;
BEDNARSKI, MD .
SCIENCE, 1993, 261 (5121) :585-588
[8]
Polystyrene-b-poly(acrylic acid) vesicle size control using solution properties and hydrophilic block length [J].
Choucair, A ;
Lavigueur, C ;
Eisenberg, A .
LANGMUIR, 2004, 20 (10) :3894-3900
[9]
Control of amphiphilic block copolymer morphologies using solution conditions [J].
Choucair, A ;
Eisenberg, A .
EUROPEAN PHYSICAL JOURNAL E, 2003, 10 (01) :37-44
[10]
Helical superstructures from charged poly(styrene)-poly(isocyanodipeptide) block copolymers [J].
Cornelissen, JJLM ;
Fischer, M ;
Sommerdijk, NAJM ;
Nolte, RJM .
SCIENCE, 1998, 280 (5368) :1427-1430