Complex and liquid hydrides for energy storage

被引：79

作者：

Callini, Elsa ^{[1
,2
]}

Atakli, Zuleyha Oezlem Kocabas ^{[2
]}

Hauback, Bjorn C. ^{[3
]}

Orimo, Shin-ichi ^{[13
]}

Jensen, Craig ^{[14
]}

Dornheim, Martin ^{[11
]}

Grant, David ^{[12
]}

Cho, Young Whan ^{[10
]}

Chen, Ping ^{[8
]}

Hjorvarsson, Bjorgvin ^{[15
]}

de Jongh, Petra ^{[7
]}

Weidenthaler, Claudia ^{[16
]}

Baricco, Marcello ^{[4
,5
]}

Paskevicius, Mark ^{[6
]}

Jensen, Torben R. ^{[6
]}

Bowden, Mark E. ^{[9
]}

Autrey, Thomas S. ^{[9
]}

Zuettel, Andreas ^{[1
,2
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn ISIC, EPFL Valais Wallis, Lab Mat Renewable Energy, Sion, Switzerland

[2] EMPA Mat Sci & Technol, Uberlandstr 129, CH-8600 Sion, Switzerland

[3] Inst Energy Technol, Dept Phys, N-2007 Kjeller, Norway

[4] Univ Turin, Dept Chem, Turin, Italy

[5] Univ Turin, NIS, Turin, Italy

[6] Aarhus Univ, Interdisciplinary Nanosci Ctr, Dept Chem, Ctr Mat Crystallog, Langelandsgade 140, DK-8000 Aarhus C, Denmark

[7] Univ Utrecht, Debye Inst Nanomat Sci, Univ Weg 99, NL-3584 CG Utrecht, Netherlands

[8] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

[9] Pacific NW Natl Lab, 902 Battelle Blvd,POB 999, Richland, WA 99352 USA

[10] Korea Inst Sci & Technol, High Temp Energy Mat Res Ctr, Future Convergence Res Div, Hwarangno 14 Gil 5, Seoul 136791, South Korea

[11] Helmholtz Zentrum Geesthacht, Dept Nanotechnol, Mat Technol, D-21502 Geesthacht, Germany

[12] Univ Pk, Nottingham NG7 2RD, England

[13] Tohoku Univ, Inst Mat Res, WPI Adv Inst Mat Res, Sendai, Miyagi, Japan

[14] Univ Hawaii, Dept Chem, 2545 Mall, Honolulu, HI 96822 USA

[15] Dept Phys & Astron, Mat Phys, POB 516, S-75120 Uppsala, Sweden

[16] Max Planck Inst Kohlenforsch, Dept Heterogeneous Catalysis, Kaiser Wilhelm Pl 1, D-45470 Mulheim, Germany

来源：

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2016年 / 122卷 / 04期

基金：

英国工程与自然科学研究理事会; 新加坡国家研究基金会;

关键词：

REVERSIBLE HYDROGEN STORAGE; LITHIUM ALUMINUM-HYDRIDE; SOLVENT-FREE SYNTHESIS; N-H SYSTEM; METAL BOROHYDRIDES; THERMAL-PROPERTIES; ALKALI-METAL; CHLORIDE-SUBSTITUTION; NANOCONFINED LIBH4; DEHYDROGENATION BEHAVIOR;

D O I：

10.1007/s00339-016-9881-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The research on complex hydrides for hydrogen storage was initiated by the discovery of Ti as a hydrogen sorption catalyst in NaAlH4 by Boris Bogdanovic in 1996. A large number of new complex hydride materials in various forms and combinations have been synthesized and characterized, and the knowledge regarding the properties of complex hydrides and the synthesis methods has grown enormously since then. A significant portion of the research groups active in the field of complex hydrides is collaborators in the International Energy Agreement Task 32. This paper reports about the important issues in the field of complex hydride research, i.e. the synthesis of borohydrides, the thermodynamics of complex hydrides, the effects of size and confinement, the hydrogen sorption mechanism and the complex hydride composites as well as the properties of liquid complex hydrides. This paper is the result of the collaboration of several groups and is an excellent summary of the recent achievements.

引用

页数：22

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