An unexpected trimethylstannylpyrrole from a stannylated derivative of tosylmethyl isocyanide (TosMIC) and chalcone

被引：2

作者：

Meetsma, A ^{[1
]}

Dijkstra, HP ^{[1
]}

tenHave, R ^{[1
]}

vanLeusen, AM ^{[1
]}

机构：

[1] UNIV GRONINGEN,GRONINGEN CTR CATALYSIS & INORGAN CHEM,DEPT ORGAN & MOL INORGAN CHEM,NL-9747 AG GRONINGEN,NETHERLANDS

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷 / pt 11期

关键词：

D O I：

10.1107/S0108270196009286

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the title compound, tert-butyl 3-benzoyl-4-phenyl-2- (trimethylstannyl)pyrrole-N-carboxylate, [Sn(CH3)(3)(C22H20NO3)], is one of the first in which the stannyl group is attached to a C atom of the pyrrole ring, There appears to be an intramolecular interaction between the Sn atom and the carbonyl O atoms of both the benzoyl and the tert-butoxycarbonyl substituents. The compound was prepared by a base-induced cycloaddition of a stannylated derivative of tosylmethyl isocyanide to chalcone.

引用

页码：2747 / 2750

页数：4

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