Ditopic Ion Transport Systems: Anion-p Interactions and Halogen Bonds at Work

被引：196

作者：

Jentzsch, Andreas Vargas ^{[1
]}

Emery, Daniel ^{[1
]}

Mareda, Jiri ^{[1
]}

Metrangolo, Pierangelo ^{[2
,3
]}

Resnati, Giuseppe ^{[2
,3
]}

Matile, Stefan ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland

[2] Politecn Milan, NFMLab, I-20131 Milan, Italy

[3] Politecn Milan, CNSC IIT POLIMI Dept Chem Mat & Chem Engn Giulio, I-20131 Milan, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 49期

基金：

欧洲研究理事会;

关键词：

anions; anion transport; anion-p interactions; halogen bonds; CALIXARENES; SELECTIVITY; RECEPTORS; CHANNEL; SODIUM;

D O I：

10.1002/anie.201104966

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single-atom exchange series are introduced to extract the individual contributions of halogen bonds and anion-π interactions to the transport of anions across lipid bilayer membranes (see picture). Known cation binding sites are used for counterion activation of the neutral calix[4]arene transporters. The experimental evidence for anion transport with halogen bonds is unprecedented. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11675 / 11678

页数：4

共 59 条

[1] Inclusion of organic cations by calix[n] arenes [J].

Abraham, W .

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2002, 43 (3-4) :159-174

[2] Interaction of anions with perfluoro aromatic compounds [J].

Alkorta, I ;

Rozas, I ;

Elguero, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (29) :8593-8598

[3]

[Anonymous], 2011, ANGEW CHEM

[4]

[Anonymous], 2011, ANGEW CHEM, DOI DOI 10.1002/ANIE.201007560

[5]

[Anonymous], 2011, ANGEW CHEM INT EDIT, DOI DOI 10.1002/ANIE.201100208

[6]

[Anonymous], 2010, ANGEW CHEM

[7]

[Anonymous], 2008, Angew. Chem, DOI DOI 10.1002/ANGE.200800128

[8] Halogen bonds in biological molecules [J].

Auffinger, P ;

Hays, FA ;

Westhof, E ;

Ho, PS .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2004, 101 (48) :16789-16794

[9] Resorcin[4]arene cavitand-based molecular switches [J].

Azov, VA ;

Beeby, A ;

Cacciarini, M ;

Cheetham, AG ;

Diederich, F ;

Frei, M ;

Gimzewski, JK ;

Gramlich, V ;

Hecht, B ;

Jaun, B ;

Latychevskaia, T ;

Lieb, A ;

Lill, Y ;

Marotti, F ;

Schlegel, A ;

Schlittler, RR ;

Skinner, PJ ;

Seiler, P ;

Yamakoshi, Y .

ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (02) :147-156

[10] CARRIER-MEDIATED TRANSPORT THROUGH BULK LIQUID MEMBRANES - DEPENDENCE OF TRANSPORT RATES AND SELECTIVITY ON CARRIER PROPERTIES IN A DIFFUSION-LIMITED PROCESS [J].

BEHR, JP ;

KIRCH, M ;

LEHN, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (01) :241-246

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