The self-assembly of [60] fullerene-substituted 2,2′-bipyridine on the surface of Au(111) and Au nanoparticles

被引:24
作者
Du, CM [1 ]
Xi, B [1 ]
Li, YL [1 ]
Wang, C [1 ]
Wang, S [1 ]
Shi, ZQ [1 ]
Fang, HJ [1 ]
Xiao, SX [1 ]
Zhu, DB [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
关键词
D O I
10.1039/b103541j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The cycloaddition reaction of the azide of 4,4'-dimethyl-2,2'-bipyridine to [60]fullerene was used to synthesize a novel [60]fullerene derivative, which was employed to self-assemble on the surface of Au(111) and gold nanoparticles. Scanning tunneling microscopy results show that the [60]fullerene derivative forms a self-assembled monolayer on the Au(111) surface spontaneously. Transmission electron micrographs indicate the presence of spherical particles with an average radius of about 10 nm in the nanoparticle preparations.
引用
收藏
页码:1191 / 1194
页数:4
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