para-Connected Cyclophenylenes and Hemispherical Polyarenes: Building Blocks for Single-Walled Carbon Nanotubes?

被引：110

作者：

Bunz, Uwe H. F. ^{[1
]}

Menning, Sebastian ^{[1
]}

Martin, Nazario ^{[2
,3
]}

机构：

[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany

[2] Univ Complutense, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain

[3] IMDEA Nanociencia, Madrid 28048, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 29期

关键词：

alkynes; carbon; macrocycles; nanotubes; polyarenes; BOTTOM-UP SYNTHESIS; GEODESIC POLYARENES; SELECTIVE SYNTHESIS; CHEMICAL-SYNTHESIS; STEP; C-60; ELUCIDATION; MACROCYCLES; FULLERENES; CHALLENGES;

D O I：

10.1002/anie.201201494

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon nanotubes by design? Cyclo-para-phenylenes are monomers for the synthesis of armchair carbon nanotubes (see picture, right), and are also attractive fluorophores that display size-dependent emission properties. Geodesic polyarenes represent a realistic alternative for the rational design of carbon nanotubes through the chemical elongation of the hydrocarbon template (left). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7094 / 7101

页数：8

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