The efficiency and mechanism of γ-alumina catalytic ozonation of 2-methylisoborneol in drinking water

被引:15
作者
Chen, L. [1 ]
Qi, F. [1 ]
Xu, B. [1 ]
Xu, Z. [1 ]
Shen, J. [1 ]
Li, K. [1 ]
机构
[1] Harbin Inst Technol, Sch Municipal Environm Engn, Harbin 150090, Peoples R China
来源
5th World Water Congress: Drinking Water Treatment Processes | 2006年 / 6卷 / 03期
关键词
gamma-alumina; 2-methylisoborneol; hydroxyl radicals; pH(zpc); surface hydroxyl groups;
D O I
10.2166/ws.2006.726
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The efficiency and mechanism in degradation of 2-methylisoborneol (MIB) as a taste and odour compound in drinking water were studied under the condition where gamma-alumina catalysed ozonation. As a result, gamma-alumina can show distinct activity in enhancing the efficiency of ozonation of MIB. Tert-butyl alcohol had a remarkable effect on the removal efficiency of catalytic ozonation of MIB. The surface charge status, surface hydroxyl group status of gamma-alumina, and pH values of the solution can be linked together. When the pH value of the solution was near the pH(zpc). of gamma-Al2O3, there was observable activity in the catalysed ozonation process. R-ct, which denoted the relative concentration of hydroxyl radical ((OH)-O-.), was much higher in the catalysed ozonation process than in the ozonation process. This result further illuminated that gamma-Al2O3 can promote ozone decomposition to produce (OH)-O-.. Finally, the effect of r(p/l) on catalysed ozone decomposition and ozone decomposition was investigated.
引用
收藏
页码:43 / 51
页数:9
相关论文
共 21 条
[1]  
*AWWA RES FDN COMP, 1991, OZ WAT TREATM APPL E
[2]   DETERMINATION OF OZONE IN WATER BY THE INDIGO METHOD [J].
BADER, H ;
HOIGNE, J .
WATER RESEARCH, 1981, 15 (04) :449-456
[3]   CRITICAL-REVIEW OF RATE CONSTANTS FOR REACTIONS OF HYDRATED ELECTRONS, HYDROGEN-ATOMS AND HYDROXYL RADICALS (.OH/.O-) IN AQUEOUS-SOLUTION [J].
BUXTON, GV ;
GREENSTOCK, CL ;
HELMAN, WP ;
ROSS, AB .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1988, 17 (02) :513-886
[4]  
CHEN L, 2004, CHINESE ENV SCI TECH, V27, P143
[5]   Hydroxyl radical ozone ratios during ozonation processes.: I-The Rct concept [J].
Elovitz, MS ;
von Gunten, U .
OZONE-SCIENCE & ENGINEERING, 1999, 21 (03) :239-260
[6]   Comparison of an ordered mesoporous aluminosilicate, silica, alumina, titania and zirconia in normal-phase high-performance liquid chromatography [J].
Grun, M ;
Kurganov, AA ;
Schacht, S ;
Schuth, F ;
Unger, KK .
JOURNAL OF CHROMATOGRAPHY A, 1996, 740 (01) :1-9
[7]  
HOIGNE J, 1983, WATER RES, V17, P185, DOI 10.1016/0043-1354(83)90099-4
[8]   RATE CONSTANTS OF REACTIONS OF OZONE WITH ORGANIC AND INORGANIC-COMPOUNDS IN WATER .3. INORGANIC-COMPOUNDS AND RADICALS [J].
HOIGNE, J ;
BADER, H ;
HAAG, WR ;
STAEHELIN, J .
WATER RESEARCH, 1985, 19 (08) :993-1004
[9]   RATE CONSTANTS OF REACTIONS OF OZONE WITH ORGANIC AND INORGANIC-COMPOUNDS IN WATER .1. NON-DISSOCIATING ORGANIC-COMPOUNDS [J].
HOIGNE, J ;
BADER, H .
WATER RESEARCH, 1983, 17 (02) :173-183
[10]   Chemistry of alumina, reactions in aqueous solution and its application in water treatment [J].
Kasprzyk-Hordern, B .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2004, 110 (1-2) :19-48