Dioxin like compounds from municipal waste incinerator emissions: Assessment of the presence of polychlorinated naphthalenes

被引:66
作者
Abad, E [1 ]
Caixach, J [1 ]
Rivera, J [1 ]
机构
[1] CSIC, CID, Dept Ecotechnol, Mass Spectrometry Lab, ES-08034 Barcelona, Spain
关键词
D O I
10.1016/S0045-6535(98)00177-5
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Polychloronaphthalenes (PCN) were identified and quantified in emission samples Collected from five different municipal waste incinerators (MWI). Polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzofulans (PCDF) were also determined to find a possible relationship between these classes of organochlorinated compounds. The analyses of PCDD/PCDF and PCN were carried out by high resolution gas chromatography coupled with high resolution mass spectrometry using a positive electron ionization source and operating in the selected ion monitoring analyzer mode (HRGC-HRMS/EI(+)-SIM). The total levels of PCN varied from 1.08 up to 21.36 ng/Nm(3) (mono- to octachlorinated) and 0.33 to 5.72 ng/Nm(3) (tetra- to octachlorinated), whereas the levels of PCDD/PCDF ranged between 1.14 and 276.26 ng/Nm(3) (0.01 and 5 ng I-TEQ/Nm(3)), depending on the type of the MWI. These findings do not corroborate a PCN and PCDD/PCDF correlation. (C)1998 Elsevier Science Ltd. All rights reserved.
引用
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页码:109 / 120
页数:12
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