Oxidative addition of chlorinated solvents (eg CH2Cl2 and CHCl3) with rhodium(I) complexes;: crystal structure of mer-[Rh(py)3(CH2Cl)Cl2]

被引：44

作者：

Bradd, KJ ^{[1
]}

Heaton, BT ^{[1
]}

Jacob, C ^{[1
]}

Sampanthar, JT ^{[1
]}

Steiner, A ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 07期

关键词：

D O I：

10.1039/a809652j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Common chlorinated solvents (e.g. CH2Cl2 and CHCl3) readily reacted with [Rh-2(C8H14)(4)(mu-Cl)(2)] (C8H14 = cyclooctene), in the presence of a monodentate, nitrogen donor ligand (L = py or 4-Bu(t)py), to give the oxidative addition product [RhL3RCl2] (R = CH2Cl, CHCl2 or CH2Ph) which for R = CH2Cl and CH2Ph has been shown by X-ray analysis to adopt the mer configuration. NMR Spectroscopic measurements (C-13 and N-15) in solution were consistent with this configuration, although these NMR data cannot unambiguously distinguish between the mer and fac isomers.

引用

页码：1109 / 1112

页数：4

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