Oxidation by CO2 of Au0 species on La2O3-supported gold clusters

被引:26
作者
Mihaylov, Mihail [1 ,2 ]
Ivanova, Elena [1 ,2 ]
Hao, Yalin [3 ]
Hadjiivanov, Konstantin [1 ]
Gates, Bruce C. [3 ]
Knoezinger, Helmut [2 ]
机构
[1] Bulgarian Acad Sci, Inst Gen & Inorgan Chem, Sofia 1113, Bulgaria
[2] Univ Munich, Phys Chem, Dept Chem & Biochem, Munich, Germany
[3] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA
关键词
D O I
10.1039/b713106b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The IR spectra that characterize La2O3-supported gold clusters show that the original Au-0 species can be oxidized by CO2 during the catalytic CO oxidation reaction, indicating that CO2 is the actual gold oxidizing agent.
引用
收藏
页码:175 / 177
页数:3
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