Impenetrable barriers in phase-space

被引：201

作者：

Wiggins, S

Wiesenfeld, L

Jaffé, C

Uzer, T

机构：

[1] Univ Bristol, Sch Math, Bristol BS8 1TW, Avon, England

[2] Univ Grenoble 1, Spectrometrie Phys Lab, F-38402 St Martin Dheres, France

[3] W Virginia Univ, Dept Chem, Morgantown, WV 26506 USA

[4] Georgia Inst Technol, Sch Phys, Ctr Nonlinear Sci, Atlanta, GA 30332 USA

来源：

PHYSICAL REVIEW LETTERS | 2001年 / 86卷 / 24期

关键词：

D O I：

10.1103/PhysRevLett.86.5478

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Dynamical systems theory is used to construct a general phase-space version of transition state theory. Special multidimensional separatrices are found which act as impenetrable barriers in phase-space between reacting and nonreacting trajectories. The elusive momentum-dependent transition state between reactants and products is thereby characterized. A practical algorithm is presented and applied to a strongly coupled Hamiltonian.

引用

页码：5478 / 5481

页数：4

共 23 条

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[Anonymous], 2002, Mathematical aspects of classical and celestial mechanics

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