Golden opportunities in stereoselective catalysis

被引：380

作者：

Bongers, Nadine ^{[1
]}

Krause, Norbert ^{[1
]}

机构：

[1] Dortmund Univ Technol, D-44227 Dortmund, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 12期

关键词：

chirality transfer; cycloisomerization; enantioselectivity; gold; ion pairs;

D O I：

10.1002/anie.200704729

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A golden future: The recent discoveries in stereoselective gold catalysis are extremely promising. Transfer of chirality or the generation of new stereogenic centers from prochiral substrates on application of chiral gold catalysts occur with excellent enantioselectivities. New concepts, such as the use of gold catalysts with chiral counterions, help to improve selectivities (see scheme, dppm=bis(diphenylphosphanyl) methane). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：2178 / 2181

页数：4

相关论文

共 46 条

[11] Gold-catalyzed organic reactions [J].

Hashmi, A. Stephen K. .

CHEMICAL REVIEWS, 2007, 107 (07) :3180-3211

[12] Gold catalysis [J].

Hashmi, A. Stephen K. ;

Hutchings, Graham J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (47) :7896-7936

[13] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE METAL-COMPLEXES [J].

HAYASHI, T .

PURE AND APPLIED CHEMISTRY, 1988, 60 (01) :7-12

[14] The golden gate to catalysis [J].

Hoffmann-Röder, A ;

Krause, N .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (03) :387-391

[15] Gold(III) chloride catalyzed cyclization of α-hydroxyallenes to 2,5-dihydrofurans [J].

Hoffmann-Röder, A ;

Krause, N .

ORGANIC LETTERS, 2001, 3 (16) :2537-2538

[16] Gold-catalyzed and N-iodosuccinimide-mediated cyclization of γ-substituted allenamides [J].

Hyland, Christopher J. T. ;

Hegedus, Louis S. .

JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (22) :8658-8660

[17] CATALYTIC ASYMMETRIC ALDOL REACTION - REACTION OF ALDEHYDES WITH ISOCYANOACETATE CATALYZED BY A CHIRAL FERROCENYLPHOSPHINE-GOLD(I) COMPLEX [J].

ITO, Y ;

SAWAMURA, M ;

HAYASHI, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (20) :6405-6406

[18] Molecular diversity through gold catalysis with alkynes [J].

Jimenez-Nunez, Eloisa ;

Echavarren, Antonio M. .

CHEMICAL COMMUNICATIONS, 2007, (04) :333-346

[19] Gold(I)-catalyzed stereoselective olefin cyclopropanation [J].

Johansson, MJ ;

Gorin, DJ ;

Staben, ST ;

Toste, FD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (51) :18002-18003

[20]

Krause N, 2002, SYNTHESIS-STUTTGART, P1759

← 1 2 3 4 5 →