Sequential elimination-cyclopropanation reactions promoted by samarium:: Highly diastereoselective synthesis of cyclopropylamides

被引：17

作者：

Concellón, JM ^{[1
]}

Rodríguez-Solla, H ^{[1
]}

Llavona, R ^{[1
]}

机构：

[1] Univ Oviedo, Dept Quim Organ & Inorgan, E-33071 Oviedo, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 03期

关键词：

D O I：

10.1021/jo0262098

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

trans-Cyclopropanamides were obtained, in high yield, from 2-chloro-3-hydroxyamides by a sequenced elimination-cyclopropanation process promoted by Samarium/diiodomethane or Samarium diiodide and Samarium/diiodomethane.

引用

页码：1132 / 1133

页数：2

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