Enhanced velocity of surfactant binding after the volume collapse of an oppositely charged gel

被引:19
作者
Narita, T [1 ]
Gong, JP [1 ]
Osada, Y [1 ]
机构
[1] HOKKAIDO UNIV,GRAD SCH SCI,DIV BIOL SCI,SAPPORO,HOKKAIDO 060,JAPAN
关键词
D O I
10.1002/marc.1997.030180913
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];
摘要
This paper is a kinetic study of the interaction between an ionic surfactant and an oppositely charged polymer gel. The volume collapse of the gel enhances substantially the velocity of surfactant uptake, despite the decreased free volume for diffusion. This indicates that the increased charge density of the polymer network accelerates the surfactant binding.
引用
收藏
页码:853 / 857
页数:5
相关论文
共 8 条
[1]
ELECTROKINETIC MODELING OF THE CONTRACTILE PHENOMENA OF POLYELECTROLYTE GELS - ONE-DIMENSIONAL CAPILLARY MODEL [J].
GONG, JP ;
NITTA, T ;
OSADA, Y .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (38) :9583-9587
[2]
THEORETICAL-ANALYSIS OF THE CROSS-LINKING EFFECT ON THE POLYELECTROLYTE-SURFACTANT INTERACTION [J].
GONG, JP ;
OSADA, Y .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (27) :10971-10975
[3]
GONG JP, 1995, CHEM LETT, V6, P449
[4]
Thermosensitive polymer gel by reversible surfactant binding [J].
Isogai, N ;
Gong, JP ;
Osada, Y .
MACROMOLECULES, 1996, 29 (21) :6803-6806
[5]
KHANDURINA YV, 1994, VYSOKOMOL SOEDIN, V36, P235
[6]
KHOKHLOV AR, 1992, MAKROMOL CHEM-THEOR, V1, P105
[7]
ORDERED-AGGREGATE FORMATION BY SURFACTANT-CHARGED GEL INTERACTION [J].
OKUZAKI, H ;
OSADA, Y .
MACROMOLECULES, 1995, 28 (01) :380-382
[8]
ROLE AND EFFECT OF CROSS-LINKAGE ON THE POLYELECTROLYTE-SURFACTANT INTERACTIONS [J].
OKUZAKI, H ;
OSADA, Y .
MACROMOLECULES, 1995, 28 (13) :4554-4557