Photosensitized oxidation of citronellol in microreactors

被引：83

作者：

Meyer, Susann

Tietze, Daniel

Rau, Sven

Schaefer, Bernhard

Kreisel, Guenter

机构：

[1] Univ Jena, Inst Tech Chem & Environm Chem, D-07743 Jena, Germany

[2] Univ Jena, Inst Inorgan & Analyt Chem, D-07743 Jena, Germany

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2007年 / 186卷 / 2-3期

关键词：

microreactor; photoreaction; singlet oxygen; citronellol; LED; Ru-complex;

D O I：

10.1016/j.jphotochem.2006.08.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The present study describes the examination of a photochemical model reaction in two different reactor types: a batchreactor and a microreactor. In order to evaluate both reactors' efficiency, they had been compared in terms of their respective space-time yield and photonic efficiency. In this model reaction we performed the oxidation of citronellol by singlet oxygen generated with the aid of a photosensitizer. As sources of radiation, light emitting diodes (LED) were used for the first time. (c) 2006 Elsevier B.V. All rights reserved.

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收藏

页码：248 / 253

页数：6

相关论文

共 19 条

[1] Photosynthesis of rose oxide by concentrated sunlight in the absence of singlet oxygen [J].

Dincalp, H ;

Içli, S .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 141 (2-3) :147-151

[2]

Ehrfeld W., 2000, Microreactors: new technology for modern chemistry, DOI DOI 10.1002/3527601953

[3] Application of microstructured reactor technology for the photochemical chlorination of alkylaromatics [J].

Ehrich, H ;

Linke, D ;

Morgenschweis, K ;

Baerns, M ;

Jähnisch, K .

CHIMIA, 2002, 56 (11) :647-653

[4]

EICHER T, 1995, ORGANISCHE CHEM GRUN

[5] Photocatalysis in microreactors [J].

Gorges, R ;

Meyer, S ;

Kreisel, G .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 167 (2-3) :95-99

[6] Photooxygenation in polystyrene beads with covalently and non-covalently bound tetraarylporphyrin sensitizers [J].

Griesbeck, AG ;

El-Idreesy, TT ;

Bartoschek, A .

ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (2-3) :245-251

[7] Sustainable photochemistry: solvent-free singlet oxygen-photooxygenation of organic substrates embedded in porphyrin-loaded polystyrene beads [J].

Griesbeck, AG ;

Bartoschek, A .

CHEMICAL COMMUNICATIONS, 2002, (15) :1594-1595

[8] RU(II) POLYPYRIDINE COMPLEXES - PHOTOPHYSICS, PHOTOCHEMISTRY, ELECTROCHEMISTRY, AND CHEMI-LUMINESCENCE [J].

JURIS, A ;

BALZANI, V ;

BARIGELLETTI, F ;

CAMPAGNA, S ;

BELSER, P ;

VONZELEWSKY, A .

COORDINATION CHEMISTRY REVIEWS, 1988, 84 :85-277

[9] (S)-3,7-dimethyl-5-octene-1,7-diol and related oxygenated monoterpenoids from petals of Rosa damascena Mill. [J].

Knapp, H ;

Straubinger, M ;

Fornari, S ;

Oka, N ;

Watanabe, N ;

Winterhalter, P .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1998, 46 (05) :1966-1970

[10]

LOWE H, 2000, P 4 INT C MICR TECHN, pS31