[Cu(C24H22N4O3)]•CH2Cl2:: A discrete breathing metallamacrocycle showing selective and reversible guest adsorption with retention of single crystallinity

被引:69
作者
Dong, Yu-Bin [1 ]
Zhang, Qiang [1 ]
Liu, Li-Li [1 ]
Ma, Jian-Ping [1 ]
Tang, Bo [1 ]
Huang, Ru-Qi [1 ]
机构
[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Engn Res Ctr Pesticide & Med Intermediate Clean P, Minist Educ, Jinan 250014, Peoples R China
关键词
D O I
10.1021/ja067384z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A discrete, breathing metallamacrocycle Cu2L2 exhibits reversible and selective size-, shape-, and number-dependent guest adsorption with retention of single crystallinity. The system can exclusively recognize CHCl3 molecules from mixed CH2Cl2/CHCl3 vapor.
引用
收藏
页码:1514 / +
页数:3
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