Chains, planes, and antimonides

被引：75

作者：

Mills, AM ^{[1
]}

Lam, R ^{[1
]}

Ferguson, MJ ^{[1
]}

Deakin, L ^{[1
]}

Mar, A ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

COORDINATION CHEMISTRY REVIEWS | 2002年 / 233卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

pnictides; antimonides; rare-earth; structural chemistry;

D O I：

10.1016/S0010-8545(02)00097-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ternary rare-earth main-group pnictides RE(x)M(y)Pn(z) where M is a Group 13 or 14 element and Pn is P, As, Sb, or Bi form an emerging class of solid state compounds that frequently display extensive homoatomic M-M and Pn-Pn bonding in addition to heteroatomic M-Pn bonding in their anionic substructures. Their structures, properties, and bonding are discussed, with a focus on the antimonides, which have been most heavily investigated. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：207 / 222

页数：16

共 69 条

[1] Synthesis, structure, and magnetic properties of the rare-earth zintl compounds Eu(14)MnPn(11) and Eu(14)InPn(11) (Pn = Sb, Bi) [J].