Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques

被引：104

作者：

Tromp, M

Sietsma, JRA

van Bokhoven, JA

van Strijdonck, GPF

van Haaren, RJ

van der Eerden, AMJ

van Leeuwen, PWNM

Koningsberger, DC

机构：

[1] Debye Inst, Dept Inorgan Chem & Catalysis, NL-3508 TB Utrecht, Netherlands

[2] Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands

[3] ETH Honggerberg, Tech Chem Lab, CH-8093 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 01期

关键词：

D O I：

10.1039/b206758g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

UV-Vis, combined with ED-XAFS shows, for the first time, the evolution of inactive Pd dimers and trimers, that are a possible first stage in the deactivation process of important palladium catalysed reactions, leading to larger palladium clusters and eventually palladium black.

引用

收藏

页码：128 / 129

页数：2

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