The Solid Electrolyte Interphase - The Most Important and the Least Understood Solid Electrolyte in Rechargeable Li Batteries

被引:723
作者
Winter, Martin [1 ]
机构
[1] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany
来源
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2009年 / 223卷 / 10-11期
关键词
Solid Electrolyte Interphase (SEI); Li Battery; Lithium Ion Battery; Anode; Li Metal; Graphite; Lithium Alloy; LITHIUM-ION BATTERIES; TIN-BASED INTERMETALLICS; PROPYLENE CARBONATE; ELECTROCHEMICAL INTERCALATION; GRAPHITE; ANODE; LIQUID; DECOMPOSITION; PERFORMANCE; MECHANISMS;
D O I
10.1524/zpch.2009.6086
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this chapter, the Solid Electrolyte Interphase (SEI) concept is introduced and the different requirements on the electrolyte and on the SEI formation process in the presence of various anode materials (metallic lithium, graphitic carbons, and lithium storage metals/alloys), in particular, similarities and differences, are highlighted. The difficulties to understand and analyze the SEI characteristics and composition are discussed by examples.
引用
收藏
页码:1395 / 1406
页数:12
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