Fluctuations in electrolytes: The Lebowitz and other correlation lengths

被引:17
作者
Bekiranov, S [1 ]
Fisher, ME [1 ]
机构
[1] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA
关键词
D O I
10.1103/PhysRevLett.81.5836
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Explicit low-density expansions (using Meeron and hypernetted-chain graphical resummations) are reported for various charge and density correlation lengths in hard-sphere electrolytes with general valences, z(sigma), and diameters, a(sigma tau). The "Lebowitz length" quantifies the area law for charge fluctuations, [Q(Lambda)(2)], in a large domain Lambda; it approaches but differs from the Debye and other correlation lengths. All corresponding, universal limiting-law predictions of generalized Debye-Huckel (GDH) theory (Lee and Fisher, 1996-1997) prove exact, thus validating GDH theory as a basis for studying anomalies in Coulombic criticality.
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页码:5836 / 5839
页数:4
相关论文
共 25 条
[1]  
[Anonymous], 1998, STRONGLY COUPLED COU
[2]   ASYMPTOTIC ANALYSIS OF PRIMITIVE MODEL ELECTROLYTES AND THE ELECTRICAL DOUBLE-LAYER [J].
ATTARD, P .
PHYSICAL REVIEW E, 1993, 48 (05) :3604-3621
[3]  
BEKIRANOV S, IN RPESS PHYS REV E
[4]  
BEKIRANOV S, IN PRESS
[5]  
BEKIRANOV S, 1997, B AM PHYS SOC, V42, P725
[6]  
BRYDGES DC, IN PRESS REV MOD PHY
[7]  
FALKENHAGEN H, 1971, IONIC FLUIDS, V1
[8]  
Fisher ME, 1996, J PHYS-CONDENS MAT, V8, P9103, DOI 10.1088/0953-8984/8/47/002
[9]   Ginzburg criterion for Coulombic criticality [J].
Fisher, ME ;
Lee, BP .
PHYSICAL REVIEW LETTERS, 1996, 77 (17) :3561-3564
[10]  
HAFSKJOLD B, 1982, STUDIES STAT MECH, V8