1-Butyl-3-methylimidazolium cobalt tetracarbonyl [bmim][Co(CO)4]: a catalytically active organometallic ionic liquid

被引：127

作者：

Brown, RJC

Dyson, PJ ^{[1
]}

Ellis, DJ

Welton, T

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 18期

关键词：

D O I：

10.1039/b104601m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An ambient temperature liquid transition metal carbonyl anion has been prepared in a metathesis reaction between [bmim]Cl ([bmim](+) = 1-butyl-3-methylimidazolium cation) and Na[Co(CO)(4)]; the ionic liquid catalyses the debromination of 2-bromoketones.

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页码：1862 / 1863

页数：2

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