Breaking down barriers: The liaison between sigmatropic shifts, electrocyclic reactions, and three-center cations

被引：21

作者：

Hoffmann, R ^{[1
]}

Tantillo, DJ

机构：

[1] Cornell Univ, Dept Chem & Biol Chem, Ithaca, NY 14853 USA

[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 47期

关键词：

carbocations; electrocyclic reaction; pericyclic reaction; proton affinity; sigmatropic rearrangement; transition states;

D O I：

10.1002/anie.200352853

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Almost indistinguishable transition-state (TS) geometries, which differ only by the presence or absence of a simple proton, were found for electrocyclic and sigmatropic rearrangements with the same electron count (see picture).

引用

页码：5877 / 5882

页数：6

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