An arene-alkene photocycloaddition-radical cyclization cascade: The first syntheses of cis,cis,cis,trans-[5.5.5.5]-fenestranes

被引：36

作者：

Wender, PA

Dore, TM

deLong, MA

机构：

[1] Department of Chemistry, Stanford University, Stanford

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 43期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(96)01740-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first cis,cis,cis,trans-[5.5.5.5]-fenestranes have been synthesized in three steps using a novel arene-alkene photocycloaddition-radical cyclization cascade, which creates overall 5 new rings and 8 stereogenic centers. A lead tetraacetate mediated ring expansion of a 5,5-fused ring system, discovered in the course of exploring the chemistry of these new materials, is also described. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：7687 / 7690

页数：4

共 32 条

[1]

[Anonymous], 1991, COMPREHENSIVE ORGANI, DOI DOI 10.1016/B978-0-08-052349-1.00135-9

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