Template synthesis of [Cr(en)(3)][Te-6]: A novel polytelluride with a framework structure, whose cavities are filled with a [Cr(en)(3)](3+) template

被引：7

作者：

Reisner, C ^{[1
]}

Tremel, W ^{[1
]}

机构：

[1] UNIV MAINZ,INST ANORGAN CHEM & ANALYT CHEM,D-55099 MAINZ,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 04期

关键词：

D O I：

10.1039/a608173h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Cr(en)(3)][Te-6] (en = ethylenediamine) is obtained by a template synthesis under solvothermal conditions from Cr(CO)(6) and BaTe4; its crystal structure contains a polymeric Te-6(3-) framework whose pores contain the Cr(en)(3)(3+) template; [Cr(en)(3)][Te-6] is the first chalcogenide with a porous three-dimensional framework structure.

引用

页码：387 / 388

页数：2

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