Architecture of nanostructured polymers

被引：150

作者：

Ishizu, K ^{[1
]}

Tsubaki, K ^{[1
]}

Mori, A ^{[1
]}

Uchida, S ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Organ Mat & Macromol, Int Res Ctr Macromol Sci, Meguro Ku, Tokyo 1528552, Japan

来源：

PROGRESS IN POLYMER SCIENCE | 2003年 / 28卷 / 01期

关键词：

hyperbranched polymer; living radical polymerization; rod-like macromolecule; polymer brush;

D O I：

10.1016/S0079-6700(02)00025-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper reviews the synthesis and properties of nanostructural polymers with different macromolecular architecture. Special emphasis is placed on hyperbranched polymers, rod-like macromolecules and polymer brushes. Hyperbranched polymers were prepared by various types,of living radical mechanisms of functionalized vinyl monomers and showed hard sphere-like behavior in dilute solution with increasing degree of branching. This reflected on the compact nature of the hyperbranched macromolecules. Rod-like macromolecules were prepared by crosslinking cylindrical microdomains of block copolymers in the solid state or cylindrical micelles in solution. In general, polymer brushes were prepared by homopolymerization or copolymerization of macromonomers. Both solutions of rod-like macromolecules and polymer brushes formed a unimolecule structure even in high concentration. Thus, the particular chemical structures of rod-like macromolecules and polymer brushes were influenced significantly by densely, branched side chains. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：27 / 54

页数：28

共 171 条

[1] The ''egg-carton'' phase: A new morphology of complexes of polyelectrolytes with natural lipid mixtures [J].