Imprinted photonic polymers for chiral recognition

被引:143
作者
Hu, Xiaobin [1 ]
An, Qi [1 ]
Li, Guangtao [1 ]
Tao, Shengyang [1 ]
Liu, Ban [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Key Lab Organ Photoelect & Mol Engn, Beijing 100084, Peoples R China
关键词
colloids; macroporous materials; molecular recognition; polymers;
D O I
10.1002/anie.200601849
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A general protocol to prepare self-reporting photonic polymer films for specific enantiomer recognition is described. The combined molecular imprinting and colloidal crystal approach produces films with interconnected macroporous arrays and cavities that are complementary to the analyte. Binding of the analyte can be directly detected by the change in optical diffraction of the periodic macroporous array (see picture; PB = phosphate buffer). (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:8145 / 8148
页数:4
相关论文
共 38 条
[1]   From colour fingerprinting to the control of photoluminescence in elastic photonic crystals [J].
Arsenault, AC ;
Clark, TJ ;
Von Freymann, G ;
Cademartiri, L ;
Sapienza, R ;
Bertolotti, J ;
Vekris, E ;
Wong, S ;
Kitaev, V ;
Manners, I ;
Wang, RZ ;
John, S ;
Wiersma, D ;
Ozin, GA .
NATURE MATERIALS, 2006, 5 (03) :179-184
[2]  
Gu Z.Z., 2002, ANGEW CHEM, V114, P1201, DOI DOI 10.1002/(ISSN)1521-3757
[3]  
Gu ZZ, 2002, ANGEW CHEM INT EDIT, V41, P1153, DOI 10.1002/1521-3773(20020402)41:7<1153::AID-ANIE1153>3.0.CO
[4]  
2-4
[5]   Molecularly imprinted polymers and their use in biomimetic sensors [J].
Haupt, K ;
Mosbach, K .
CHEMICAL REVIEWS, 2000, 100 (07) :2495-2504
[6]   Polymerized colloidal crystal hydrogel films as intelligent chemical sensing materials [J].
Holtz, JH ;
Asher, SA .
NATURE, 1997, 389 (6653) :829-832
[7]   Single-crystal colloidal multilayers of controlled thickness [J].
Jiang, P ;
Bertone, JF ;
Hwang, KS ;
Colvin, VL .
CHEMISTRY OF MATERIALS, 1999, 11 (08) :2132-2140
[8]   Surface-templated nanostructured films with two-dimensional ordered arrays of voids [J].
Jiang, P .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (42) :5625-5628
[9]  
Jiang P, 2004, ANGEW CHEM, V116, P1554
[10]   Glucose-sensitive inverse opal hydrogels: Analysis of optical diffraction response [J].
Lee, YJ ;
Pruzinsky, SA ;
Braun, PV .
LANGMUIR, 2004, 20 (08) :3096-3106