Ultrasound aided photochemical synthesis of Ag loaded TiO2 nanotube arrays to enhance photocatalytic activity

被引:227
作者
Sun, Lan [1 ]
Li, Jing [1 ]
Wang, Chenglin [1 ]
Li, Sifang [1 ]
Lai, Yuekun [1 ,2 ]
Chen, Hongbo [1 ]
Lin, Changjian [1 ,2 ]
机构
[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
[2] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
基金
中国国家自然科学基金;
关键词
TiO2 nanotube array; Ag nanoparticle; Ultrasound aided photochemistry; Photocurrent; Photocatalytic degradation; THIN-FILMS; SILVER NANOPARTICLES; METAL NANOPARTICLES; AU NANOPARTICLES; ANODIC-OXIDATION; SOLAR-CELLS; FABRICATION; LAYERS; DEGRADATION; REDUCTION;
D O I
10.1016/j.jhazmat.2009.06.115
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This work presents a novel approach for preparing TiO2 nanotube array photocatalyst loaded with highly dispersed Ag nanoparticles through an ultrasound aided photochemical route. The Ag content loaded on the array was controlled by changing the concentration of AgNO3 solution. The Ag-TiO2 nanotube arrays were characterized by SEM, XRD, XPS and UV-vis absorption. The effects of Ag content on the photoelectrochemical (PEC) property and photocatalytic activity of TiO2 nanotube array electrode were studied. The results showed that Ag loading significantly enhanced the photocurrent and photocatalytic degradation rate of TiO2 nanotube array under W-light irradiation. The photocurrent and photocatalytic degradation rate of Ag-TiO2 nanotube array prepared in 0.006 M AgNO3 solution were about 1.2 and 3.7 times as that of pure TiO2 nanotube array, respectively. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1045 / 1050
页数:6
相关论文
共 37 条
[1]   Self-organized, free-standing TiO2 nanotube membrane for flow-through photocatalytic applications [J].
Albu, Sergiu P. ;
Ghicov, Andrei ;
Macak, Jan M. ;
Hahn, Robert ;
Schmuki, Patrik .
NANO LETTERS, 2007, 7 (05) :1286-1289
[2]   Effect of loaded silver nanoparticles on TiO2 for photocatalytic degradation of Acid Red 88 [J].
Anandan, S. ;
Sathishkumar, Panneerselvam ;
Pugazhenthiran, N. ;
Madhavan, J. ;
Maruthamuthu, P. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (08) :929-937
[3]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[4]   Photoelectrochemical study of organic-inorganic hybrid thin films via electrostatic layer-by-layer assembly [J].
Chen, Da ;
Wang, Geng ;
Lu, Wu ;
Zhang, Hao ;
Li, Jinghong .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (09) :2151-2156
[5]   Titanium oxide nanotube arrays prepared by anodic oxidation [J].
Gong, D ;
Grimes, CA ;
Varghese, OK ;
Hu, WC ;
Singh, RS ;
Chen, Z ;
Dickey, EC .
JOURNAL OF MATERIALS RESEARCH, 2001, 16 (12) :3331-3334
[6]   Synthesis and application of highly ordered arrays of TiO2 nanotubes [J].
Grimes, Craig A. .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (15) :1451-1457
[7]   Carbon doping of self-organized TiO2 nanotube layers by thermal acetylene treatment [J].
Hahn, Robert ;
Ghicov, Andrei ;
Salonen, Jarno ;
Lehto, Vesa-Pekka ;
Schmuki, Patrik .
NANOTECHNOLOGY, 2007, 18 (10)
[8]   Facile fabrication of Ag-Pd bimetallic nanoparticles in ultrathin TiO2-gel films:: Nanoparticle morphology and catalytic activity [J].
He, JH ;
Ichinose, I ;
Kunitake, T ;
Nakao, A ;
Shiraishi, Y ;
Toshima, N .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (36) :11034-11040
[9]   In situ synthesis of noble metal nanoparticles in ultrathin TiO2-gel films by a combination of ion-exchange and reduction processes [J].
He, JH ;
Ichinose, I ;
Kunitake, T ;
Nakao, A .
LANGMUIR, 2002, 18 (25) :10005-10010
[10]  
Hyung M.S., 2004, J PHOTOCH PHOTOBIO A, V163, P37