Modelling study of electron-beam polycyclic and nitro-polycyclic aromatic hydrocarbons treatment

被引：16

作者：

Gerasimov, Gennady ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Inst Mech, Moscow 119192, Russia

来源：

RADIATION PHYSICS AND CHEMISTRY | 2007年 / 76卷 / 01期

关键词：

PAHs and NPAHs removal; flue gases; electron-beam irradiation; reaction kinetics;

D O I：

10.1016/j.radphyschem.2005.12.042

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The efficiency of the electron-beam removal of harmful impurities from industrial flue gases was studied as applied to polycyclic and nitro-polycyclic aromatic hydrocarbons. The mathematical model of radiation-induced processes was proposed. The model includes aromatic molecules decomposition in gas-phase reactions, and their liquid-phase conversion in the aerosol droplets produced upon the binary volume condensation of water and sulfuric acid vapors. The presence of active species (atoms and radicals) in radiation zone and their reactions with aliphatic and aromatic hydrocarbons can result in an opposite effect: the formation of aromatic molecules and growth of their structure. Modelling study of such processes allows evaluating the efficiency of this purification technology at various initial conditions. Results of calculations are compared with available experimental data. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：27 / 36

页数：10

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