Platinum-catalysed cyclopropanation of olefins with ethyl diazoacetate

被引：16

作者：

Boverie, S

Simal, F

Demonceau, A

Noels, AF

Eremenko, IL

Sidorov, AA

Nefedov, SE

机构：

[1] UNIV LIEGE,MACROMOL CHEM & ORGAN CATALYSIS LAB,CERM,B-4000 LIEGE,BELGIUM

[2] NS KURNAKOV GEN & INORGAN CHEM INST,MOSCOW 117907,RUSSIA

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(97)10027-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of ethyl diazoacetate to olefins in the presence of a catalytic amount of platinum complexes provides the corresponding cyclopropanes in good to excellent yields. (C) 1997 Published by Elsevier Science Ltd.

引用

页码：7543 / 7546

页数：4

共 38 条

[1]

ABDALLAH H, 1982, TETRAHEDRON LETT, V23, P503

[2] TRANSITION-METAL-CATALYZED REACTIONS OF DIAZO-COMPOUNDS .1. CYCLOPROPANATION OF DOUBLE-BONDS [J].

ANCIAUX, AJ ;

HUBERT, AJ ;

NOELS, AF ;

PETINIOT, N ;

TEYSSIE, P .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (04) :695-702

[3] A new class of bis-oxazoline ligands for the Cu-catalysed asymmetric cyclopropanation of olefins [J].

Bedekar, AV ;

Andersson, PG .

TETRAHEDRON LETTERS, 1996, 37 (23) :4073-4076

[4] HIGHLY REACTIVE PLATINUM(0) CARBENE INTERMEDIATES IN THE REACTIONS OF DIAZO-COMPOUNDS - A FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRIC STUDY [J].

BERTANI, R ;

MICHELIN, RA ;

MOZZON, M ;

TRALDI, P ;

SERAGLIA, R ;

DASILVA, MDCG ;

POMBEIRO, AJL .

ORGANOMETALLICS, 1995, 14 (01) :551-554

[5]

BRAISH TF, 1996, APPL HOMOGENEOUS CAT, P1100

[6]

BRIGHTY KE, 1996, APPL HOMOGENEOUS CAT, P1097

[7] Study of the reactivity profile of glycine Schiff's bases with dipolarophiles: Application towards a concise synthesis of CCG-II [J].

Chavan, SP ;

Venkatraman, MS ;

Sharma, AK ;

Chittiboyina, AG .

TETRAHEDRON LETTERS, 1996, 37 (16) :2857-2858

[8] Osmium-catalysed cyclopropanation of olefins [J].

Demonceau, A ;

Lemoine, CA ;

Noels, AF .

TETRAHEDRON LETTERS, 1996, 37 (07) :1025-1026

[9] Novel ruthenium-based catalyst systems for the ring-opening metathesis polymerization of low-strain cyclic olefins [J].

Demonceau, A ;

Stumpf, AW ;

Saive, E ;

Noels, AF .

MACROMOLECULES, 1997, 30 (11) :3127-3136

[10] Cyclopropanation reactions catalysed by ruthenium complexes with new anionic phosphine ligands [J].

Demonceau, A ;

Simal, F ;

Noels, AF ;

Vinas, C ;

Nunez, R ;

Teixidor, F .

TETRAHEDRON LETTERS, 1997, 38 (23) :4079-4082

← 1 2 3 4 →