Thermal stability of reversible addition-fragmentation chain transfer/macromolecular architecture design by interchange of xanthates chain-transfer agents

被引：58

作者：

Legge, Thomas M.

Slark, Andrew T.

Perrier, Sebastien ^{[1
]}

机构：

[1] Univ Leeds, Dept Colour & Polymer Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Imperial Chem Ind, Slough SL2 5DS, Berks, England

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2006年 / 44卷 / 24期

关键词：

degradation; reversible addition fragmentation chain transfer (RAFT); thermogravimetric analysis (TGA);

D O I：

10.1002/pola.21803

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of chain-transfer agents used in reversible addition-fragmentation chain transfer/macromolecular architecture design by interchange of xanthates polymerizations were subjected to thermogravimetric analysis and gas chromatography/mass spectrometry to assess their stability to heat and to determine their degradation pathways. The effects of the chain-transfer-agent class and structure on the thermal stability are described. (c) 2006 Wiley Periodicals, Inc.

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收藏

页码：6980 / 6987

页数：8

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