Synthesis and structures of photodecarbonylated ruthenium(II) complexes - potential intermediates for mixed ligand complexes

被引：30

作者：

Deacon, GB

Kepert, CM

Sahely, N

Skelton, BW

Spiccia, L ^{[1
]}

Thomas, NC

White, AH

机构：

[1] Monash Univ, Dept Chem, Clayton, Vic 3168, Australia

[2] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 03期

关键词：

D O I：

10.1039/a808006b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Irradiation of solutions containing complexes of the type [RuL(CO)(2)Cl-2] where L is a 2,2'-bipyridine analogue leads to monodecarbonylation and the formation of dimeric ruthenium(II) complexes, [RuL(CO)(2)Cl](2), for which two different structures have been established, viz. with a hans disposition of bridging and terminal chlorides [L = di(2-pyridyl) ketone] or with CO tl ans to bridging chlorides (L = 1,10-phenanthroline).

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页码：275 / 277

页数：3

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