Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex

被引：122

作者：

Smith, JM ^{[1
]}

Lachicotte, RJ ^{[1
]}

Holland, PL ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 17期

关键词：

D O I：

10.1039/b103635c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination number of the metal in iron(II) beta -diketiminate complexes can be tuned through the size of the alkyl substituents on the ligand backbone.

引用

页码：1542 / 1543

页数：2

共 31 条

[1] Three coordinate divalent Group 14 element compounds with a β-diketiminate as supporting ligand L2MX [L2 = PhNC(Me)CHC(Me)NPh, X = Cl, I; M = Ge, Sn]
Akkari, A
Byrne, JJ
Saur, I
Rima, G
Gornitzka, H
Barrau, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 622 (1-2) : 190 - 198
[2] [Anonymous], HDB HETEROGENEOUS CA
[3] Steric blocking of methyl bridging: The syntheses and X-ray crystal structures of a three-coordinate methyl magnesium complex and its THF adduct
Bailey, PJ
Coxall, RA
Dick, CM
Fabre, S
Parsons, S
[J]. ORGANOMETALLICS, 2001, 20 (04) : 798 - 801
[4] DIAMAGNETIC REVERSIBLE PARAMAGNETIC EQUILIBRIA IN SOLUTIONS OF BIS(DIALKYLPHOSPHINO)ETHANE COMPLEXES OF IRON
BAKER, MV
FIELD, LD
HAMBLEY, TW
[J]. INORGANIC CHEMISTRY, 1988, 27 (16) : 2872 - 2876
[5] Budzelaar PHM, 1998, EUR J INORG CHEM, P1485
[6] A stable three-coordinate rhodium(I) olefin complex
Budzelaar, PHM
de Gelder, R
Gal, AW
[J]. ORGANOMETALLICS, 1998, 17 (19) : 4121 - 4123
[7] MOSSBAUER ELECTRONIC AND FAR INFRARED SPECTRAL STUDIES OF SOME TETRAHEDRAL IRON(2) COMPLEXES
BURBRIDGE, CD
GOODGAME, DM
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (05): : 1074 - +
[8] Single-site catalysts for ring-opening polymerization:: Synthesis of heterotactic poly(lactic acid) from rac-lactide
Cheng, M
Attygalle, AB
Lobkovsky, EB
Coates, GW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (49) : 11583 - 11584
[9] Catalytic reactions involving C1 feedstocks:: New high-activity Zn(II)-based catalysts for the alternating copolymerization of carbon dioxide and epoxides
Cheng, M
Lobkovsky, EB
Coates, GW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (42) : 11018 - 11019
[10] Cui CM, 2000, ANGEW CHEM INT EDIT, V39, P4274, DOI 10.1002/1521-3773(20001201)39:23<4274::AID-ANIE4274>3.0.CO

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