Absorption, fluorescence and light scattering of oligothiophene and oligophenylenevinylene nanoaggregates

被引:59
作者
Gierschner, J
Egelhaaf, HJ
Oelkrug, D
机构
关键词
oligothiophenes; oligophenylenevinylenes; nanoaggregates; molecular orientation; fluorescence anisotropy; light scattering;
D O I
10.1016/S0379-6779(97)80846-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Molecular orientations in oligothiophene (Tn) - and oligo- (p-phenylenevinylene) (Pn) - nanoaggregates are investigated by time-resolved fluorescence anisotropies and polarized light scattering. Tn- and unsubstituted Pn-molecules align parallel to each other, but not the substituted Pn's. Electronic absorption and fluorescence spectra of the oriented systems are strongly altered against the monomers and the fluorescence quantum yields are strongly reduced.
引用
收藏
页码:529 / 530
页数:2
相关论文
共 7 条
[1]  
CVETKO D, 1996, SYNTHETIC MET, V76, P173
[2]   UV/VIS AND IR SPECTROSCOPIC STUDIES ON MOLECULAR-ORIENTATION IN ULTRATHIN FILMS OF POLYTHIOPHENE MODEL COMPOUNDS [J].
EGELHAAF, HJ ;
BAUERLE, P ;
RAUER, K ;
HOFFMANN, V ;
OELKRUG, D .
JOURNAL OF MOLECULAR STRUCTURE, 1993, 293 :249-252
[3]   ORIENTATION AND MOBILITY IN ULTRATHIN OLIGOTHIOPHENE FILMS - UV-VIS, IR AND FLUORESCENCE STUDIES [J].
EGELHAAF, HJ ;
BAUERLE, P ;
RAUER, K ;
HOFFMANN, V ;
OELKRUG, D .
SYNTHETIC METALS, 1993, 61 (1-2) :143-146
[4]  
EGELHAAF HJ, 1995, P SOC PHOTO-OPT INS, V2362, P398, DOI 10.1117/12.200971
[5]  
EGELHAAF HJ, UNPUB SYNTH MET
[6]   VIBRATIONAL AND GEOMETRIC STRUCTURE OF QUATERTHIOPHENE ON AG(111) [J].
LI, R ;
BAUERLE, P ;
UMBACH, E .
SURFACE SCIENCE, 1995, 331 :100-104
[7]  
OELKRUG D, 1996, IN PRESS THIN SOLID