Gondola-shaped luminescent tetrarhenium metallacycles with crown-ether-like multiple recognition sites

被引：61

作者：

Sathiyendiran, Malaichamy

Liao, Rong-Tang

Thanasekaran, P.

Luo, Tzuoo-Tsair

Venkataramanan, N. S.

Lee, Gene-Hsiang

Peng, Shie-Ming

Lu, Kuang-Lieh ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 107, Taiwan

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 25期

关键词：

D O I：

10.1021/ic061886w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The self-assembly of gondola-shaped tetrarhenium metallacyclophanes was achieved in near quantitative yield from Re(CO)(3) corners, a ditopic heterocyclic clip, and a bischelating-bridging unit using an orthogonal-bonding approach. The highly luminescent metallacycles contain crown-ether-like recognition sites, which are capable of selectively recognizing metal ions and planar aromatic molecules.

引用

收藏

页码：10052 / 10054

页数：3

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