Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds

被引：50

作者：

Braga, D

Maini, L

Polito, M

Mirolo, L

Grepioni, F

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[2] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 24期

关键词：

D O I：

10.1039/b209861j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvent-free reactions with molecular systems have been exploited to prepare hybrid organic-organometallic solids: grinding of the complex [Fe(eta(5)-C5H4COOH)(2)] with solid bases B generates quantitatively the corresponding hydrogen bonded salts [Fe(eta(5)-C5H4COOH)(eta(5)-C5H4COO)][HB] (B = 1,4-diazabicyclo[2.2.2]octane, 1,4-phenylenediamine); gas-solid reactions are also possible with volatile bases.

引用

页码：2960 / 2961

页数：2

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