Steam demand reduction of water-gas shift reaction in IGCC power plants with pre-combustion CO2 capture

This paper presents the results of system assessments that were conducted to compare conventional and advanced water-gas shift reactor sections. The latter are specifically tailored for Integrated Gasification Combined Cycles (IGCC) power plants with pre-combustion CO2 capture. The advanced shift reactor section comprises four staged reactors with distributed feeds of synthesis gas and quench water in between the reactors. Conventional shift reactor sections consist of two sequential reactors with intermediate cooling, where the entire synthesis gas stream passes both reactors. The advanced shift reactor section reduces the steam requirement of the water-gas shift reaction up to 70% in comparison with conventional configurations, at carbon dioxide capture ratios of approximately 85%. This reduction allows for lower electric efficiency penalties, thus higher net electric outputs for IGCC power plants with CO2 capture. For each case, the CO2 capture ratio was optimised for the lowest specific lost work per amount of captured CO2. Both the number of reactors and the total catalyst volume are higher for the advanced shift reactor sections, resulting in increased capital expenses. In case of four staged reactors, the additional expenses are expected to be outperformed by the increased revenues associated with the higher net electric output. (C) 2009 Elsevier Ltd. All rights reserved.