Single crystals of stilbazolium derivatives for second-order nonlinear optics

被引：129

作者：

Yang, Z ^{[1
]}

Aravazhi, S

Schneider, A

Seiler, P

Jazbinsek, M

Günter, P

机构：

[1] ETH Honggerberg, Inst Quantum Elect, Nonlinear Opt Lab, CH-8093 Zurich, Switzerland

[2] ETH Honggerberg, Organ Chem Lab, CH-8093 Zurich, Switzerland

来源：

ADVANCED FUNCTIONAL MATERIALS | 2005年 / 15卷 / 07期

关键词：

D O I：

10.1002/adfm.200500036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of ionic stilbazolium salts with benzenesuffonates with different substituents in the para position have been synthesized. Single crystals of 4-NN-dimethylamino-4'-N'-methylstilbazoliump-methoxybenzenesulfonate (DSMOS) were successfully grown in methanol solution by slow cooling. X-ray studies revealed that DSMOS crystallized in the triclinic space group P1 with its molecular dipoles perfectly aligned in one direction-favorable for large nonlinear optical and electro-optical effects. Kurtz powder tests revealed a large powder second-harmonic generation efficiency that is similar to that of the well-studied 4-NN-dimethylamino-4'-N-methylstilbazolium tosylate (DAST).

引用

页码：1072 / 1076

页数：5

共 17 条

[1] Growth of high quality nonlinear optical crystal 4-dimethylamino-N-methyl-4-stilbazolium tosylate (DAST) [J].

Adachi, H ;

Takahashi, Y ;

Yabuzaki, J ;

Mori, Y ;

Sasaki, T .

JOURNAL OF CRYSTAL GROWTH, 1999, 198 :568-571

[2] SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[3]

Bosshard C., 1995, Organic Nonlinear Optical Materials

[4] PARA-ALKOXYBENZENESULFONIC ACID ESTERS [J].

CARR, MH ;

BROWN, HP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (05) :1170-1172

[5]

CHEMLA DS, 1987, NONLINEAR OPTICAL PR, V1

[6]

Coe BJ, 2002, ADV FUNCT MATER, V12, P110, DOI 10.1002/1616-3028(20020201)12:2<110::AID-ADFM110>3.0.CO

[7]

2-Y

[8] A POWDER TECHNIQUE FOR EVALUATION OF NONLINEAR OPTICAL MATERIALS [J].

KURTZ, SK ;

PERRY, TT .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1968, QE 4 (05) :333-+

[9] Organic thin film crystal growth for nonlinear optics:: present methods and exploratory developments [J].

Manette, S ;

Ehrensperger, M ;

Bosshard, C ;

Günter, P .

COMPTES RENDUS PHYSIQUE, 2002, 3 (04) :449-462

[10] ORGANIC SALTS WITH LARGE 2ND-ORDER OPTICAL NONLINEARITIES [J].

MARDER, SR ;

PERRY, JW ;

YAKYMYSHYN, CP .

CHEMISTRY OF MATERIALS, 1994, 6 (08) :1137-1147

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