Synthesis of unsymmetrical vicinal diols using titanium aminotroponiminate alkyl complexes

被引：23

作者：

Steinhuebel, DP ^{[1
]}

Lippard, SJ ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 02期

关键词：

D O I：

10.1021/om980927w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel, multicomponent method to prepare vicinal diols from titanium dialkyl complexes, CO, and carbonyl compounds is presented. The reaction involves sequential coupling of aminotroponiminate-supported titanium dialkyl complexes, carbon monoxide, and carbonyl compounds to yield vicinal diols following hydrolysis of the diolate complexes.

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页码：109 / 111

页数：3

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