Self-assembly of rectangles and prisms via a molecular "clip"

被引：46

作者：

Kim, D

Paek, JH

Jun, MJ

Lee, JY

Kang, SO ^{[1
]}

Ko, JJ

机构：

[1] Korea Univ, Dept Chem, Jochiwon 339700, Chungnam, South Korea

[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

[3] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 22期

关键词：

D O I：

10.1021/ic0508369

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aromatic molecular "clips" bearing two symmetrically bound platinum moieties have been prepared. The molecular "clip" 4 readily self-assembled with linear linkers such as 4,4'-bipyridyl, 1,4-bis[2-(4-isocyano-3,5-diisopropylphenyl)ethynyl]benzene, and nicotinic acid to form molecular rectangles. The overall dimensions of the rectangle 7 were 7.3 angstrom x 15.3 angstrom. The molecular "clip" also self-assembled with tritopic pyridyl and isocyanide ligands to form trigonal prismatic frameworks. The characterization of the supramolecules by multinuclear NMR, electrospray mass spectrometry, and X-ray crystal structures is also reported.

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页码：7886 / 7894

页数：9

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