Acid-doped polybenzimidazole as the membrane of electrochemical hydrogen sensors

被引:49
作者
Bouchet, R
Siebert, E
Vitter, G
机构
[1] Lab. d'Electrochimie Physchim. M., ENSEEG, 38402 Saint Martin d'Hères, Domaine Universitaire
关键词
D O I
10.1149/1.1837622
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Aprotonic polymer electrolyte based on polybenzimidazole is proposed for use in a hydrogen sensor, operating at room temperature, in air. The potentiometric response in inert gas containing hydrogen obeys the Nernst equation. In air, the EMF is a mixed potential which results from the hydrogen oxidation and the oxygen reduction. The response time is of the order of 30 s whatever the hydrogen concentration step within the hydrogen partial pressure range from 10(-3) to 1 atm.
引用
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页码:L95 / L97
页数:3
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