Pyrolysis of sawdust in a conical spouted bed reactor.: Yields and product composition

被引:174
作者
Aguado, R [1 ]
Olazar, M [1 ]
José, MJS [1 ]
Aguirre, G [1 ]
Bilbao, J [1 ]
机构
[1] Univ Basque Country, Dept Ingn Quim, E-48080 Bilbao, Spain
关键词
D O I
10.1021/ie990309v
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The performance of original equipment provided with a conical spouted bed reactor has been studied in flash pyrolysis of sawdust with an inert gas (N-2) in the 350-700 degrees C range and with 50 ms of average gas residence time. The effect of pyrolysis temperature on the yields of gas, liquid, and char on gas and liquid composition and on char properties has been studied. The maximum yield of liquid (corresponding to 70 wt %) is obtained at 450 degrees C and its composition determined by GC/MS is similar to that reported in the literature for bubbling fluidized beds. Although temperatures above 600 degrees C are required for the development of the char porous structure, the yield of CO2 obtained under these conditions is unacceptable.
引用
收藏
页码:1925 / 1933
页数:9
相关论文
共 38 条
[1]  
AGUADO R, 1999, THESIS U BASQUE COUN
[2]   INFLUENCE OF PHYSICAL AND CHEMICAL-PARAMETERS ON WOOD PYROLYSIS [J].
BEAUMONT, O ;
SCHWOB, Y .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1984, 23 (04) :637-641
[3]   REACTOR DEVELOPMENT FOR THE ULTRAPYROLYSIS PROCESS [J].
BERG, DA ;
BRIENS, CL ;
BERGOUGNOU, MA .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1989, 67 (01) :96-101
[4]   PRODUCT DISTRIBUTION IN THE FLASH PYROLYSIS OF LIGNOCELLULOSIC MATERIALS IN A FLUIDIZED-BED [J].
BILBAO, R ;
MILLERA, A ;
ARAUZO, J .
FUEL, 1988, 67 (11) :1586-1588
[5]  
BILBAO R, 1989, AFINIDAD, V46, P275
[6]  
Bridgwater A.V., 1991, Biomass Pyrolysis Liquids Upgrading and Utilisation, DOI [10.1007/978-94-011-3844-4_2, DOI 10.1007/978-94-011-3844-4_2]
[7]   OPPORTUNITIES FOR BIOMASS PYROLYSIS LIQUIDS PRODUCTION AND UPGRADING [J].
BRIDGWATER, AV ;
COTTAM, ML .
ENERGY & FUELS, 1992, 6 (02) :113-120
[8]  
CHOI CK, 1978, Patent No. 4101412
[9]   Heat, momentum and mass transport through a shrinking biomass particle exposed to thermal radiation [J].
DiBlasi, C .
CHEMICAL ENGINEERING SCIENCE, 1996, 51 (07) :1121-1132
[10]   Additives to lower and stabilize the viscosity of pyrolysis oils during storage [J].
Diebold, JP ;
Czernik, S .
ENERGY & FUELS, 1997, 11 (05) :1081-1091