Synthesis and reactivity of (1-fluorovinyl) phenyl sulfoxide as a dienophile

被引：19

作者：

Hanamoto, T ^{[1
]}

Korekoda, K ^{[1
]}

Nakata, K ^{[1
]}

Handa, K ^{[1
]}

Koga, Y ^{[1
]}

Kondo, M ^{[1
]}

机构：

[1] Saga Univ, Dept Chem & Appl Chem, Saga 8408502, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2002年 / 118卷 / 1-2期

关键词：

(1-fluorovinyl) phenyl sulfoxide; Diels-Alder reaction; mono-fluorinated building block; 1,3-diphenylisobenzofuran;

D O I：

10.1016/S0022-1139(02)00198-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(1-Fluorovinyl) phenyl sulfoxide 2 was prepared in two steps from (1-fluorovinyl)methyldiphenylsilane. Although the sulfoxide 2 underwent Diels-Alder reaction with very reactive diene, 1,3-diphenylisobenzofuran, to give the corresponding fluorinated-naphthalene derivative in one step, it did not afford cycloadducts with other dienes employed. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：99 / 101

页数：3

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